【學(xué)術(shù)報(bào)告】Boranes?and?Frustrated?Lewis?Pairs:?Searching?for?New?Reactions
日期：2024-10-10
閱讀：860
主題：Boranes?and?Frustrated?Lewis?Pairs:?Searching?for?New?Reactions
報(bào)告人：Prof.?Gerhard?Erker
時間：2024年10月10日（周四）15:30-17:00
地點(diǎn)：張江科學(xué)園6號樓2樓宣講廳
邀請人：陳朝煌 副教授
報(bào)告簡介
The?talk?will?focus?on?some?selected?recent?advances?in?main?group?element?chemistry.?The unusual?reactions?of?“frustrated?Lewis?pairs”?(FLPs)?are?presented?and?discussed.?These?pairsare,?for?instance,?composed?of?phosphane/borane?combinations?whose?molecular?design effectively?hinders?them?to?undergo?the?usual?neutralization?reaction?by?Lewis?adduct formation.?FLPs?may?undergo?metal?reminiscent?small?molecule?activation?reactions?–?this?is illustrated?by?their?heterolytic?dihydrogen?splitting?ability?and?use?in?metal-free?catalytic hydrogenation.?A?variety?of?additional?FLP?small?molecule?reactions?will?be?presented.?In addition,?some?specially?designed?borane?reactions?will?be?discussed,?including?selective borole?and?borapyramidane?formation.
個人簡介
Gerhard?Erker教授是國際著名有機(jī)金屬化學(xué)家，歐洲科學(xué)院院士，曾任德國國家基金會副主席，德國化學(xué)會主席，曾獲德意志聯(lián)邦共和國功績勛章、日本化學(xué)會榮譽(yù)會士等榮譽(yù)。主要研究領(lǐng)域包括受阻Lewis酸堿對，硼化學(xué)，有機(jī)金屬化學(xué)以及高分子化學(xué)等。此外，Gerhard?Erker教授至今已培養(yǎng)和指導(dǎo)了141名博士研究生和70名博士后，共發(fā)表約770篇國際權(quán)威學(xué)術(shù)期刊論文、著作等。
