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俞煒教授

電子郵件:[email protected]
通訊地址:上海市東川路800號化學(xué)化工學(xué)院A樓501室

  • 教育背景

    1992-1996:上海交通大學(xué)應(yīng)用化學(xué)系,本科

    1996-2001:上海交通大學(xué)化學(xué)化工學(xué)院,博士(材料學(xué))

  • 工作經(jīng)歷

    2001-2002:加拿大Laval大學(xué)化工系和大分子研究中心,博士后

    2003-2004:上海交通大學(xué)化學(xué)化工學(xué)院,講師

    2005-2008:上海交通大學(xué)化學(xué)化工學(xué)院,副教授

    2006至今 :上海交通大學(xué)流變學(xué)研究所,常務(wù)副所長

    2009至今 :上海交通大學(xué)化學(xué)化工學(xué)院,教授,博士生導(dǎo)師

  • 研究方向

    復(fù)雜流體流變學(xué)與動力學(xué): 
    polymer melts and solutions, block copolymers, polymer composites/nanocomposites, emulsions, suspensions, gels
    化學(xué)流變學(xué): 
    kinetics and mechanism of chemical reactions in polymeric systems under flow field
    相轉(zhuǎn)變與臨界現(xiàn)象:
    liquid-solid transition, liquid-liquid phase separation, crystallization of polymers
    本構(gòu)模型與多尺度計算機模擬: 
    rheological constitutive theory for polymer melts/polymer blends/composites, multiscale simulation of polymer blend/composites, simulation of polymer processing
    高性能聚合物材料: 
    microporous membranes, polymer alloys, vitrimers, polymer foams, gels

  • 科研項目

    國家杰出青年科學(xué)基金、國家自然科學(xué)基金重大項目、國家重點基礎(chǔ)研究發(fā)展計劃(973計劃)、國家自然科學(xué)基金重點項目、國家自然科學(xué)基金面上項目等。



  • 代表性論文專著

    2022

    1. Jun Zhao, Zhaoming Zhang, Lin Cheng(程林), Ruixue Bai, Dong Zhao, Yongming Wang, Wei Yu, and Xuzhou Yan*, “Mechanically interlocked vitrimers”, J. Am. Chem. Soc. 2022, 144, 2, 872-882 https://doi.org/10.1021/jacs.1c10427

    2. Handing Wang, Xiang Yan, Xin Tang, Yulong Ma, Xiaoqiang Fan, Wei Li*, Wei Yu, Jingdai Wang, and Yongrong Yang, “Contribution of the initially entangled state and particle size to the sintering kinetics of UHMWPE”, Macromolecules 2022, 55, 1310-1320 https://doi.org/10.1021/acs.macromol.1c02058

    3. Yanjie Wang(王艷潔), Wei Yu, Sijun Liu*, “Physically cross-linked gellan gum/hydrophobically associated polyacrylamide double network hydrogel for cartilage repair”, European Polymer Journal 2022, 167, 111074 https://doi.org/10.1016/j.eurpolymj.2022.111074

    4. Zhaoming Zhang, Jun Zhao, Zhewen Guo, Hao Zhang(張昊), Hui Pan, Qian Wu, Wei You(尤偉), Wei Yu, Xuzhou Yan*, “Mechanically interlocked networks cross-linked by a molecular necklace”, Nature Comm. 2022, 13, 1393 https://doi.org/10.1038/s41467-022-29141-7 

    5. Ce Shang(尚策), Zhongqiang Xiong(熊鐘強), Sijun Liu, Wei Yu*, “Molecular dynamics of azobenzene polymer with photoreversible glass transition”, Macromolecules 2022, 55, 3711-3722 https://doi.org/10.1021/acs.macromol.2c00073

    6. Mingchao Ma(馬鳴超), Wenzhi Cui(崔文志), Yunlong Guo, Wei Yu*, “Adsorption-desorption effect on physical aging in PMMA-silica nanocomposites”, Polymer, 2022, 255, 125124 https://doi.org/10.1016/j.polymer.2022.125124

    7. Marouen Zammali, Sijun Liu*, Wei Yu, “A Flexible, Transparent, Ultralow Detection Limit Capacitive Pressure Sensor”, Adv. Mater. Interfaces 2022, 9, 2200015 https://doi.org/10.1002/admi.202200015

    8. 王一名,尤偉,俞煒*,聚甲基丙烯酸甲酯/聚醋酸乙烯酯/納米二氧化硅體系的相分離行為研究,高分子學(xué)報,2022,53(08),962-972.

    https://doi.org/10.11777/j.issn1000-3304.2022.22041 

    9. Lin Cheng#(程林), Xinyang Zhao#(趙鑫陽), Jun Zhao, Sijun Liu, Wei Yu*, “Structure and Dynamics of Associative Exchange Dynamic Polymer Networks”, Macromolecules 2022, 55(15), 6598–6608. https://doi.org/10.1021/acs.macromol.2c01057

    10. Zhongqiang Xiong(熊鐘強), Wei Yu*, “A nonlinear constitutive model for entangled symmetric dendrimers”, J. Rheol. 2022, 66(5), 907-923. https://doi.org/10.1122/8.0000483

    11. Luoxing Xiang, Siqi Yuan, Faxing Wang, Zhihan Xu, Xiuhong Li, Feng Tian, Liang Wu, Wei Yu, and Yiyong Mai*, “Porous Polymer Cubosomes with Ordered Single Primitive Bicontinuous Architecture and Their Sodium–Iodine Batteries”, J. Am. Chem. Soc. 2022, 144(34), 15497-15508. https://doi.org/10.1021/jacs.2c02881

    12. Xiang Liu(劉香), Wenzhi Cui(崔文志), Wei Yu*, “Interfacial Chain Entanglements Induced Melt Memory Effect in Poly(ε-caprolactone)/Silica Nanocomposites”, Chinese J. Polym. Sci. 2022, 40 (11), 1451-1465. https://doi.org/10.1007/s10118-022-2814-1 

    13. Guangfeng Li#, Jun Zhao#, Zhaoming Zhang,* Xinyang Zhao(趙鑫陽), Lin Cheng(程林), Yuhang Liu, Zhewen Guo, Wei Yu, and Xuzhou Yan*, “Robust and Dynamic Polymer Networks Enabled by Woven Crosslinks”, Angew. Chem. Int. Ed. 2022, e202210078. https://doi.org/10.1002/anie.202210078

    14. Hao Zhang(張昊), Wei You, Fenggang Bian, and Wei Yu*, “Heterogeneous Percolation in Poly(methylvinylsiloxane)/Silica Nanocomposites: The Role of Polymer–Particle Interaction”, Macromolecules 2022, 55, 19, 8834–8845 https://doi.org/10.1021/acs.macromol.2c01615

    15. Xue Yang#, Lin Cheng#(程林), Zhaoming Zhang#, Jun Zhao, Ruixue Bai, Zhewen Guo, Wei Yu*, and Xuzhou Yan*, "Amplification of integrated microscopic motions of high-density [2]rotaxanes in mechanically interlocked networks", Nature Comm. 2022, 13, 6654 https://doi.org/10.1038/s41467-022-34286-6 


  • 榮譽獎勵

    第6屆“馮新德高分子獎”提名獎 (2012年)
    教育部新世紀(jì)優(yōu)秀人才計劃 (2011年)
    第5屆“馮新德高分子獎”提名獎 (2011年)
    Polymer Processing Society, Morand Lambla Award (2010年)
    上海交通大學(xué)晨星學(xué)者獎勵(2010年)
    中國化學(xué)會青年化學(xué)獎(2009年)
    上海高校優(yōu)秀青年教師(2008年)
    上海交通大學(xué)優(yōu)秀教師三等獎(2006年)
    中國流變學(xué)青年獎(2005年)

  • 人才需求

    課題組常年招聘具有高分子化學(xué)、材料化學(xué)、化學(xué)工程、高分子物理、高分子加工、流變學(xué)、力學(xué)等相關(guān)專業(yè)背景的博士后,待遇從優(yōu),歡迎來信咨詢。

  • 文件共享

    非線性流變學(xué):大振幅振蕩剪切(large amplitude oscillatory shear, LAOS)

    1.      振蕩剪切流動

    當(dāng)給樣品施加正弦的應(yīng)變或應(yīng)力時,所產(chǎn)生的流動稱為振蕩剪切流動,流動由所施加應(yīng)變或應(yīng)力的幅度和頻率控制。所施加應(yīng)變幅度很小時,樣品產(chǎn)生的應(yīng)力響應(yīng)是有相位角的正弦信號;當(dāng)施加應(yīng)變幅度增加時,應(yīng)力響應(yīng)逐漸偏離正弦波。隨著應(yīng)變幅度的增加,應(yīng)力-應(yīng)變、應(yīng)力-應(yīng)變速率曲線(Lissajous曲線)逐漸偏離橢圓。

    1642239420881247.png

    Carbopol微凝膠在不同幅度振蕩應(yīng)力下的應(yīng)力-應(yīng)變(a)和應(yīng)力-應(yīng)變速率(b)Lissajous曲線

    2.      傅里葉變換流變學(xué)

    解析振蕩剪切行為最直接的方法是利用傅里葉變換,將時間域的信號轉(zhuǎn)換到頻率域,由倍頻信號的強度判斷偏離正弦信號的程度[1]。由于對稱性,剪切應(yīng)力應(yīng)該只出現(xiàn)奇數(shù)倍頻,而法向應(yīng)力差只出現(xiàn)偶數(shù)倍頻[3-4]。利用基頻信號定義的是應(yīng)變趨于零時的線性黏彈性函數(shù)(對應(yīng)于小振幅振蕩剪切SAOS),類似的可以定義高階倍頻下的特征模量[11],最常用的是三階倍頻特征函數(shù)(對應(yīng)于中等振幅振蕩剪切MAOS)。傅里葉變換流變學(xué)的缺點在于高階倍頻下的特征函數(shù)缺乏明確的物理意義。大量的研究表明,MAOS和LAOS特征函數(shù)能夠比SAOS特征函數(shù)更敏感的表示出材料結(jié)構(gòu)的細(xì)微差別[6,7,8]。

    1642239437838130.png

    剪切應(yīng)力隨時間的變化(a)及其傅里葉變換(b),

    第一法向應(yīng)力差隨時間的變化(c)及其傅里葉變換(d),

    烯烴嵌段共聚物的儲能模量G’11,0(e)與三倍頻特征函數(shù)Q3,0(f)

    3.      幾何平均分析

    另一種解析LAOS行為的方法是幾何平均方法[5],即通過閉合應(yīng)力-應(yīng)變曲線對應(yīng)力或應(yīng)變?nèi)∷阈g(shù)平均,得到平均應(yīng)力-應(yīng)變曲線和應(yīng)力-平均應(yīng)變曲線;對應(yīng)力-應(yīng)變速率曲線可得到類似的平均曲線。幾何平均曲線在特定條件下可以通過Chebyshev多項式建立與傅里葉變換流變學(xué)的關(guān)系[2]。幾何平均方法不依賴于LAOS的實驗方法(控制應(yīng)變或控制應(yīng)力),特別適合復(fù)雜流體(如屈服應(yīng)力流體)屈服轉(zhuǎn)變[10]、壁面滑移[9]等方面研究。

    1642239460819626.png

    應(yīng)力-應(yīng)變曲線的幾何平均(a)和應(yīng)力-應(yīng)變速率曲線的幾何平均(b),

    表征屈服轉(zhuǎn)變的應(yīng)力分岔(c),平均應(yīng)力-應(yīng)變速率關(guān)系確定壁面滑移特征(d)

    代表性論文

    1. Jianye Liu, Wei Yu*, Chixing Zhou, “Evaluation on the degrading behavior of melt polyolefin elastomer with dicumyl peroxide in oscillatory shear flow by Fourier transform rheology”, Polymer, 2008, 49, 268-277 https://doi.org/10.1016/j.polymer.2007.11.014

    2. Wei Yu*, Peng Wang, Chixing Zhou, "General stress decomposition in nonlinear oscillatory shear flow", Journal of Rheology, 2009, 53(1), 215-238 https://doi.org/10.1122/1.3037267

    3. Ying Guo, Wei Yu*, Yuanze Xu, Chixing Zhou,"Correlations between Local Flow Mechanism and Macroscopic Rheology in Concentrated Suspensions under Oscillatory Shear", Soft Matter, 2011, 7, 2433-2443 https://doi.org/10.1039/C0SM00970A

    4. 杜宇,楊凱,俞煒*,周持興,觸變/非觸變水凝膠的傅里葉變換流變學(xué)研究,高分子學(xué)報,2012, 12, 1376-1382 http://web.gfzxb.org/article/doi/10.3724/SP.J.1105.2012.12197 

    5. Wei Yu*, Yu Du, Chixing Zhou, "A New Geometric Decomposition in Nonlinear Oscillatory Shear", Journal of Rheology, 2013, 57, 1147-1175 https://doi.org/10.1122/1.4805093

    6. Peng He, Wei Yu*, Chixing Zhou, "Mesophase Separation Transitions in Polydisperse Olefin Multiblock Copolymer Melts", Macromolecules, 2014, 47, 807-820 https://doi.org/10.1021/ma402330a

    7. Zhijun Nie, Wei Yu*, Chixing Zhou, “Nonlinear rheological behavior of multiblock copolymers under large amplitude oscillatory shear”, Journal of Rheology, 2016, 60(6), 1161-1179. https://doi.org/10.1122/1.4961483

    8. Kai Yang, Jun Wang, Wei Yu*, "Two dimensional mechanical correlation analysis on nonlinear oscillatory shear flow of yield stress fluids", Korean-Austrialian Rheology Journal, 2016, 28(3), 175-180 https://doi.org/10.1007/s13367-016-0017-4 

    9. Kai Yang, Wei Yu*, “Dynamic wall slip behavior of yield stress fluids under large amplitude oscillatory shear”, Journal of Rheology, 2017, 61(4), 627-641 https://doi.org/10.1122/1.4982704

    10. Kai Yang, Zhiwei Liu, Jun Wang, Wei Yu*, Chixing Zhou, “Stress bifurcation in large amplitude oscillatory shear of yield stress fluids”, Journal of Rheology, 2018, 62, 89-106  https://doi.org/10.1122/1.4986062

    11. Zhiwei Liu, Zhongqiang Xiong, Zhijun Nie, Wei Yu*, “Correlation between linear and nonlinear material functions under large amplitude oscillatory shear”, Physics of Fluids, 2020, 32, 093105 https://doi.org/10.1063/5.0021792



地址:上海市東川路800號 200240
電話:021-54742893
E-mail:[email protected]

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